From what I understand, California is a lovely place but it's major cities are very expensive to live compared to other area of the US. Depending on what kind of employment you're after... California has Silicon Valley, of course... but if you're not specifically tech industry then I'd suggest keeping your options open.
Having said that, I can see the romantic side of upping sticks and moving to California, just like so many before you seeking better life and adventure Whatever you do, I wish you the best of fortune =)